Band gap narrowing of titanium dioxide (TiO2) nanocrystals by electrochemically active biofilms and their visible light activity.

نویسندگان

  • Shafeer Kalathil
  • Mohammad Mansoob Khan
  • Sajid Ali Ansari
  • Jintae Lee
  • Moo Hwan Cho
چکیده

We report a simple biogenic-route to narrow the band gap of TiO2 nanocrystals for visible light application by offering a greener method. When an electrochemically active biofilm (EAB) was challenged with a solution of Degussa-TiO2 using sodium acetate as the electron donor, greyish blue-colored TiO2 nanocrystals were obtained. A band gap study showed that the band gap of the modified TiO2 nanocrystals was significantly reduced (E(g) = 2.85 eV) compared to the unmodified white Degussa TiO2 (E(g) = 3.10 eV).

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عنوان ژورنال:
  • Nanoscale

دوره 5 14  شماره 

صفحات  -

تاریخ انتشار 2013